CFCs and their alternatives function as working fluids or insulating agents (heat transfer barriers) in energy-dependent systems or processes.
Assessment of the impact of CFC alternatives on global warming must consider both the direct contribution of the alternatives as greenhouse gases and the indirect contribution of the carbon dioxide emissions resulting from the energy required to operate the system over its normal life.
The sum of the direct and indirect emissions of greenhouse gases represents the "total equivalent warming impact" (TEWI) of the technologies being compared.
TEWI confirms the importance of energy efficiency and emissions reduction for refrigeration, air conditioning and solvent cleaning systems. HCFCs and HFCs are a key to obtaining superior energy efficiency.
 
 
 
 
         AFEAS and the U.S. Department of Energy (DOE) have co-funded three studies using a systems approach to determine the overall contribution of CFC alternatives to global warming. The first study, which was conducted in 1991, focused on those technical options that could be implemented by the year 2000 in each of the major CFC application areas - refrigeration, air conditioning, insulation, and solvent cleaning. The time frame was defined by the CFC phaseout schedule under the 1990 version of the Montreal Protocol.  


Figure 1. Radiative forcing of greenhouse gases (in Kg of CO2 from a refrigerator/freezer
         The second study, conducted in 1993/94, evaluated the energy and global warming impacts of next generation fluorocarbons as well as not-in-kind (NIK)/non-fluorocarbon technologies that could be developed or improved to replace CFCs and HCFCs. A third study, initiated in 1996, focuses on insulation, refrigeration, and air conditioning technologies that can be commercialized during the phaseout of HCFCs.  
         The AFEAS/DOE studies assessed the direct contribution of greenhouse gases used to make or operate the systems and the indirect contribution of the carbon dioxide emissions resulting from the energy required to run the systems over their normal lives. Both must be taken into account when determining the total global warming impact of a system. The sum of the direct and indirect emissions of greenhouse gases represents the "total equivalent warming impact" (TEWI) of the technologies being compared. The calculated TEWI is sensitive to assumptions of the system lifetime, emission losses, and the integration time horizon chosen to calculate global warming potential (GWP) values as well as the source and consumption of energy.  
         The upper graph of Figure 1 illustrates the release of the refrigerant, blowing agent, and CO2 from energy use associated with a household refrigerator. The effects of the CO2 build up as electricity is used during the lifetime of the appliance, and then drop off sharply and decay in time. The release of the blowing agent is indicated by a sharp peak when the refrigerator is removed from service after 20 years of use and assumed to be crushed upon disposal. A narrow region below the curve for the blowing agent represents the effects of the refrigerant, also assumed to be released at the end of the service life. The global warming effects of the refrigerator are represented by the area under the curves from time zero for a designated number of years. Both the blowing agent and the refrigerant are completely accounted for within 100 years; the CO2 resulting from use of the refrigerator will continue to contribute to global warming even 500 years later.  
         The lower graph in Figure 1 represents the effects from the release of a single kilogram of CO2. The total equivalent warming impact, or TEWI, for a system is the area under the curves in Figure 1a out to a certain number of years (typically 100 years) divided by the area under the curve in Figure 1b for the same number of years. The number of years chosen is referred to as the integration time horizon, or ITH. A very long ITH accounts for all of the global warming impacts, but could put too little emphasis on short-term effects. Short ITHs also lack balance in that they understate the significant long-term effects of CO2 emissions.  
         Results of the AFEAS/DOE studies show that, where data are available for comparison, it is essential to analyze the direct and indirect contributions of all alternatives to be able to choose the most environmentally acceptable option. The main conclusions from the studies follow. 
 
The use of non-fluorocarbon and NIK technologies may expand in already established niche markets, and other NIK technologies may find new market applications. But it appears unlikely that conventional and HFC technologies can be displaced to any large degree in the foreseeable future.
The studies showed that energy efficiency is a powerful tool to mitigate future potential climate change. In most applications, HFCs are the most efficient and safest available technology.
In many applications, NIK technologies will need to compete with the demonstrated continuing improvements in efficiency, emissions control, and product reclamation of conventional refrigeration, air conditioning, insulating, and cleaning/drying technologies.
 
 
 
 

The TEWI reports are available for download by clicking the links below:

         TEWI-I Energy and Global Warming Impacts of CFC Alternative Technologies (1991)          14.2 Mb - PDF          48 min via 56K modem
5 min via cable/DSL
         TEWI-II Energy and Global Warming Impacts of Not In Kind and Next Generation CFC and HCFC Alternatives (1994)          6.5 Mb - PDF          22 min via 56K modem
2.5 min via cable/DSL
         TEWI-III Report Energy and Global Warming Impacts of HFC Refrigerants and Emerging Technologies (1997)          0.8 Mb - PDF          2.8 min via 56K modem
20 sec via cable/DSL
 
 
 
 
 
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